Madhvi's art practice has been informed by the transitions of her peripatetic life - the opportunities and challenges of her constant relocations. She investigates different perspectives in her works exploring the intersection between personal and collective memories. The rhythm of repetition is the cornerstone of Madhvi's practice and her installations are often made up of multiples that tend to be immersive and experiential.

Madhvi has been invited to several biennales and triennials, among them are IOTA2021, Perth, Australia, Gyeonggi International Ceramic Biennale 2019, Korea, Indian Ceramics Triennale, 2018, Jaipur, India, China Ceramic Biennale, 2016, Henan Museum, China and Jakarta Ceramic Biennale, 2014, Jakarta, Indonesia.
Her works are in several private collections and in institutions such as India Heritage Centre, Singapore, Fule India Museum, China and Shigaraki Ceramic Cultural Centre, Japan.
Madhvi is a founding member and co-curator of Indian Ceramics Triennale and is associated with various international arts organisations such as UNESCO affiliated, International Academy of Ceramics (Geneva) and Sculpture Society Singapore. She also serves on the advisory board of Hampi Art Labs, India.
Madhvi shows with Chemould Prescott Road in Mumbai and lives and works between Mumbai and Singapore.